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Preparation of Mesoporous SBA-16 Silica-Supported Biscinchona Alkaloid Ligand for the Asymmetric Dihydroxylation of Olefins

dc.contributor.authorSarkar, Shaheen M.
dc.contributor.authorAli, Md. Eaqub
dc.contributor.authorRahman, Md. Lutfor
dc.contributor.authorYusoff, Mashitah Mohd
dc.date.accessioned2023-12-20T12:10:37Z
dc.date.available2023-12-20T12:10:37Z
dc.date.copyright2014
dc.date.issued2014-06-15
dc.identifier.citationSarkar, S. M., Ali, Md. E., Rahman, L., Yusoff, M. M. (2014) Preparation of Mesoporous SBA-16 Silica-Supported Biscinchona Alkaloid Ligand for the Asymmetric Dihydroxylation of Olefins, Journal of Nanomaterials, 2014, Article ID 123680. https://doi.org/10.1155/2014/123680.en_US
dc.identifier.issn1687-4129
dc.identifier.urihttps://research.thea.ie/handle/20.500.12065/4701
dc.description.abstractOptically active cinchona alkaloid was anchored onto mesoporous SBA-16 silica and the as-prepared complex was used as a heterogeneous chiral ligand of osmium tetraoxide for the asymmetric dihydroxylation of olefins. The prepared catalytic system provided 90–93% yield of vicinal diol with 92–99% enantioselectivity. The ordered mesoporous SBA-16 silica was found to be a valuable support for the cinchona alkaloid liganded osmium catalyst system which is frequently used in chemical industries and research laboratories for olefin functionalization.en_US
dc.formatapplication/pdfen_US
dc.language.isoengen_US
dc.publisherHindawi Publishing Corporationen_US
dc.relation.ispartofJournal of Nanomaterialsen_US
dc.rightsAttribution 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/us/*
dc.subjectcinchona alkaloiden_US
dc.subjectmesoporous SBA-16 silicaen_US
dc.subjectheterogeneous chiral liganden_US
dc.subjectosmium tetraoxideen_US
dc.subjectsymmetric dihydroxylation of olefinsen_US
dc.subjectvicinal diolen_US
dc.subjectolefin functionalizationen_US
dc.titlePreparation of Mesoporous SBA-16 Silica-Supported Biscinchona Alkaloid Ligand for the Asymmetric Dihydroxylation of Olefinsen_US
dc.typeinfo:eu-repo/semantics/articleen_US
dc.contributor.affiliationTechnological University of the Shannon: Midlands Midwesten_US
dc.description.peerreviewyesen_US
dc.identifier.doihttps://doi.org/10.1155/2014/123680en_US
dc.identifier.endpage5en_US
dc.identifier.orcidhttps://orcid.org/0000-0002-7741-678Xen_US
dc.identifier.startpage1en_US
dc.identifier.volume2014en_US
dc.rights.accessrightsinfo:eu-repo/semantics/openAccessen_US
dc.subject.departmentDepartment of Applied Scienceen_US
dc.type.versioninfo:eu-repo/semantics/publishedVersionen_US


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Except where otherwise noted, this item's license is described as Attribution 3.0 United States