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Preparation of Mesoporous Silica-Supported Chiral Amino Alcohols for the Enantioselective Addition of Diethylzinc to Aldehyde and Asymmetric Transfer Hydrogenation to Ketones

dc.contributor.authorSarkar, Shaheen M.
dc.contributor.authorAli, Md. Eaqub
dc.contributor.authorRahman, Md. Lutfor
dc.contributor.authorYusoff, Mashitah Mohd
dc.date.accessioned2023-12-20T12:45:09Z
dc.date.available2023-12-20T12:45:09Z
dc.date.copyright2015
dc.date.issued2015-08-26
dc.identifier.citationSarkar, S. M., Ali, Md, E., Rahman, L., Yusoff, M. M. (2015) Preparation of Mesoporous Silica-Supported Chiral Amino Alcohols for the Enantioselective Addition of Diethylzinc to Aldehyde and Asymmetric Transfer Hydrogenation to Ketones, Journal of Nanomaterials, 2015, Article ID 381836. https://doi.org/10.1155/2015/381836en_US
dc.identifier.issn1687-4129
dc.identifier.urihttps://research.thea.ie/handle/20.500.12065/4703
dc.description.abstractOptically active (−)-ephedrine, (−)-ephedrine, and (−)-prolinol were immobilized onto cubic mesoporous MCM-48 silica. The immobilized amino alcohols served as a heterogeneous chiral catalyst for the asymmetric addition of diethylzinc to aldehydes and transfer hydrogenation to ketones. The developed catalytic process yielded optically enriches secondary aromatic alcohols with 92–99% conversion and 70–82% enantioselectivity.en_US
dc.formatapplication/pdfen_US
dc.language.isoengen_US
dc.publisherHindawi Publishing Corporationen_US
dc.relation.ispartofJournal of Nanomaterialsen_US
dc.rightsAttribution 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/us/*
dc.subject-ephedrineen_US
dc.subject-ephedrineen_US
dc.subject-prolinolen_US
dc.subjectcubic mesoporous MCM-48 silicaen_US
dc.subjectheterogeneous chiral catalysten_US
dc.subjectimmobilized amino alcoholsen_US
dc.subjectasymmetric addition of diethylzinc to aldehydesen_US
dc.subjecttransfer hydrogenation to ketonesen_US
dc.titlePreparation of Mesoporous Silica-Supported Chiral Amino Alcohols for the Enantioselective Addition of Diethylzinc to Aldehyde and Asymmetric Transfer Hydrogenation to Ketonesen_US
dc.typeinfo:eu-repo/semantics/articleen_US
dc.contributor.affiliationTechnological University of the Shannon: Midlands Midwesten_US
dc.description.peerreviewyesen_US
dc.identifier.doihttps://doi.org/10.1155/2015/381836en_US
dc.identifier.endpage6en_US
dc.identifier.orcidhttps://orcid.org/0000-0002-7741-678Xen_US
dc.identifier.startpage1en_US
dc.identifier.volume2015en_US
dc.rights.accessrightsinfo:eu-repo/semantics/openAccessen_US
dc.subject.departmentDepartment of Applied Scienceen_US
dc.type.versioninfo:eu-repo/semantics/publishedVersionen_US


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Except where otherwise noted, this item's license is described as Attribution 3.0 United States